鈥淪ee, it just looks like a pile of sand,鈥 says post-doctoral researcher John Howard, pointing to the dirty-white chalk-like powder.
But this is no ordinary pile of sand. It came from a mix of ingredients that, when heated to 300 degrees Celsius, forms a new kind of material that, Howard says, could represent the next big leap in battery technology.
Howard is part of a team of 51吃瓜黑料 researchers led by Yusheng Zhao, head of the university鈥檚 new energy materials lab. Fueled by $2.9 million in grant funding from the U.S. Department of Energy, Zhao, Howard, and their team are making advances in fundamental research about energy storage and transfer that could change what鈥檚 inside the batteries that power our personal gadgets and electric vehicles.
鈥淲e want battery-powered vehicles that go faster, go farther, and are safer,鈥 Zhao says.
Their current focus involves development of a substance called lithium-rich antiperovskite, or LiRAP for short. (LiRAP is an electronically inverted form of 鈥減erovskite,鈥 a crystal structure that鈥檚 abundant deep in the Earth鈥檚 mantle.) When synthesized in 51吃瓜黑料鈥檚 labs, LiRAP forms the basis of a new battery material Zhao and his team are working to develop. If their effort succeeds, it would lead to a new generation of batteries that could compete with current technology at a fraction of the cost while also providing added safety benefits.
To facilitate the ion transfer that generates energy, all batteries consist of three parts 鈥 a cathode, an anode, and an electrolyte in between. Zhao explains that current lithium-ion batteries contain a liquid electrolyte that is toxic, flammable, and leak-prone. For vehicles that rely on lithium-ion batteries, including airplanes and electric cars, leakage and combustion can be serious issues. Boeing鈥檚 highly touted new 787, for example, was initially plagued by batteries that could overheat and catch fire; similarly, electric vehicle manufacturers have faced concerns over fires resulting from routine car accidents.
Zhao鈥檚 battery material 鈥 the sand-like substance produced in his lab 鈥 creates a solid electrolyte that is impact-resistant and nonflammable, making it less dangerous and more environmentally friendly. Such innovations, Zhao says, are key to his lab鈥檚 success.
Recently, his team found a way to replace a typical carbon anode (the battery part indicated by a minus sign) with one made of lithium. The change increased the battery鈥檚 energy density, which could lead to more compact batteries able to provide more energy.
鈥淭his kind of discovery is why we do what we do,鈥 Zhao says. 鈥淭he unexpected is what makes research exciting.鈥
If the team鈥檚 work continues to go well, the resulting technology could lead to a new generation of batteries constructed as singular solid-state cells 鈥 cells that could safely and efficiently power devices ranging from phones and laptops to wearable electronics and electric cars.
Initial funding for Zhao鈥檚 battery lab came from the Advanced Research Projects Agency-Energy (ARPA-E), a federal initiative supporting important applied research related to energy. Competition for ARPA-E grants is intense, with about 1 percent of proposals receiving funds. Zhao鈥檚 $2.9 million grant, awarded in 2013, funds the lab at 51吃瓜黑料 for three years and also facilitates collaboration with researchers at University of Texas and Los Alamos National Laboratory, where Zhao worked prior to joining the 51吃瓜黑料 faculty.
Zhao credits his work at Los Alamos for laying the foundation for his current research at 51吃瓜黑料. He came to the university in 2010 to lead the High Pressure Science and Engineering Center. That work led to the research now being conducted at 51吃瓜黑料鈥檚 new energy materials laboratory, he says.
Zhao says research exploring materials to serve as solid-state electrolytes in batteries has been conducted for decades, but only recently was his team able to secure the resources necessary to take significant next steps.
鈥淲e are not just working on one battery component,鈥 Zhao explains. 鈥淲e are considering the battery as a whole. Our experiments serve as a bridge between fundamental science and practical applications.鈥
He cautions, however, that there is still much to explore. The team is currently working on crystal-structure manipulation, for example, to increase ionic conductivity and power capacity. They also are investigating the LiRAP electrolyte鈥檚 compatibility with different electrode materials, as well as exploring the LiRAP material鈥檚 functionality as a cathode (the plus-sign part of a battery).
鈥淒r. Zhao is conducting cutting-edge research in battery and battery-related technologies,鈥 says Zachary Miles, associate vice president of economic development at 51吃瓜黑料. 鈥淭he collaboration with ARPA-E has created some innovative opportunities for energy research with commercial promise, and we are enthusiastic about the future of this team鈥檚 work.鈥